Linear elastic properties of single-walled carbon nanotubes

 

Fig11

The SWNT can be viewed as an infinite graphene sheet wrapped into a cylinder. Therefore, one can expect that its axial elasticity will be similar to the in-plane one of graphene apart from some effects of the tube curvature. The attempts to estimate the axial elastic moduli of any nanotube immediately face the difficulty of defining the tube cross-sectional area. Indeed, the elastic moduli are strictly defined only for homogeneous media when any choice of the cross-sectional area will give the same result. In the case of nanotubes, one can assume that a nanotube is a homogeneous cylinder with inner and outer radii, r and R, respectively.  The choice of these radii is quite ambiguous and so are the derived elastic moduli. There are several ways to overcome this difficulty by defining the linear stiffness as the axial force per unit tube perimeter or the axial force per atomic volume. When the moduli, derived by various techniques, are normalized in any of the two ways, they are very close to the in-plane ones of graphene.

 

Another important point is the radius dependence of the elastic moduli. The results of the various approaches show softening of the moduli at small tube radii. The usual technique to estimate the moduli is based on the calculation of the energy of the axially strained tube. Another technique estimates the moduli from the slope of the LA and TW phonon branches of the phonon dispersion of the nanotubes calculated using a phenomenological lattice-dynamical model [1]. Instead of obtaining the slope of the branches numerically, one can use expressions for the moduli derived in the long-wavelength limit of the lattice dynamics of the nanotubes [2]. The MWNTs can be treated in the same way as SWNTs.

 

The elastic moduli of a number of chiral and achiral SWNTs are calculated within the long-wavelength limit of the lattice dynamics based on force constants of the valence force field type [1,2].  The Young's and shear moduli, Y and G, are normalized on the atomic volume and are given in units of eV. It is clear from Fig. 1 that for a given radius Y for armchair tubes is slightly larger than for zigzag tubes while for chiral tubes it has intermediate values. It tends to about 55 eV for large radii and softens to about 50 eV for small radii. G tends to about 23 eV for large radii and softens at small radii. Both moduli exhibit slight chirality dependence.

Using Y and G, we can estimate the Poisson ratio, v, that is equal to the ratio of the relative radial expansion to the relative axial tube shortening, making use of the expression valid for the three-dimensional isotropic medium v = (Y/2 – G)/G. The spread in the values of both moduli has as a consequence a spread in the values of Poisson ratio that is more prominent for small tube radii. In the limit of large radii, Y, G, and v are equal to the experimental in-plane ones within several per cent.

 

Fig. 1. Calculated Young’s and shear moduli times the volume per atom of the tube va (in eV), and Poisson ratio estimated using the relation ν = (Y/2 – G)/G (inset) versus tube radius for various chiral and achiral SWNTs [2]. The letters A and Z stand for “armchair” and “zigzag”, respectively.

 

References

 

1. V. N. Popov, V. E. Van Doren, and M. Balkanski, Phys. Rev. B 59 (1999) 8355-8358.

2. V. N. Popov, V. E. Van Doren, and M. Balkanski, Phys. Rev. B 61 (2000) 3078-3084.

 

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Valentin Popov

6 September 2005